This relation can create physical, emotional and sexual attraction. However, Libra will find Scorpio more overwhelming at times. The secret of joy is to find a common point to share which gives pleasure and satisfaction to both.There is a mutual attraction between Libra's charming allure and Scorpio's sex appeal.
Scorpio-Libra Compatibility

Libra is the sign of relationships, whether it's amorous affairs, best buddies, extreme enemies or close kith and kin.And Scorpio is the sign of sex and deep desires.Those lovely librans always aim to be balanced, which means they pretend not to get excited about anything.But Scorpios are some of those fortunate folk who can entice a few shakes, rattles and rolls out their Libran lovers. Libra-Scorpio Compatibility With their never-ending need to be one half of a harmonious happy family, Librans think they like to be possessed, in a mental as well as a physical fashion.Sometimes the infinite intensity of the Scorpio can be a wee bit too much for the mentally-motivated Libran, who likes to keep life light and airy. As long as they can keep their cuddles caring and caressing without becoming complicated and claustrophobic, both lovers should be laughing.

Aries (Mar 21-Apr 19) Taurus (April 20 - May 20) Gemini (May 21 - Jun 21)
Cancer(June 22 - July 22) Leo (July 23 - Aug 22) Virgo (Aug 23 - Sept 22)
Libra (Sep 23 - Oct 22) Scorpio (Oct 23 - Nov 21) Sagittarius(Nov 22-Dec 21)
Capricorn (Dec 22 - Jan 19) Aquarius (Jan 20 - Feb 18) Pisces (Feb 19 - Mar 20)

In general the above Generic compatibility analysis hold good for all zodiac signs. If you are looking for in-depth compatibility analysis or if you are a professional astrologer the below analysis of Zodiac signs Compatibility - between different gender of zodiac signs will give you detailed answer. Click the below link to learn more.

Scorpio Man

Scorpio Man Compatibility

Scorpio Man and Libra Woman

Scorpio Woman

Scorpio Woman Compatibility

Scorpio Woman and Libra Man